 |
International Journal for Research Trends and Innovation
International Peer Reviewed & Refereed Journals, Open Access Journal
ISSN Approved Journal No: 2456-3315 | Impact factor: 8.14 | ESTD Year: 2016
Scholarly open access journals, Peer-reviewed, and Refereed Journals, Impact factor 8.14 (Calculate by google scholar and Semantic Scholar | AI-Powered Research Tool) , Multidisciplinary, Monthly, Indexing in all major database & Metadata, Citation Generator, Digital Object Identifier(DOI)
|
Issue: September 2023
Volume 8 | Issue 9
Review Result and Publication of Paper within : 2-3 days
Click Here For more DetailsFor Authors
Forms / Download
Published Issue Details
Editorial Board
Other IMP Links
Facts & Figure
Impact Factor : 8.14
Issue per Year : 12
Volume Published : 8
Issue Published : 88
Article Submitted : 8770
Article Published : 4497
Total Authors : 11673
Total Reviewer : 551
Total Countries : 86
Indexing Partner
Licence
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License
|
Published Paper Details
|
|
| Paper Title: | Ruthenium (III) Catalyzed Oxidation of Sugar Alcohols by N-chlorophthalimide |
| Authors Name: | Sachin Kumar Shrivastava , K.N. Sharma |
| Download E-Certificate: | Download |
| Author Reg. ID: |
IJRTI_185061
|
| Published Paper Id: | IJRTI2301008 |
| Published In: | Volume 8 Issue 1, January-2023 |
| DOI: | |
| Abstract: | Ru(III) catalysed oxidation of sugar alcohols (sorbitol and xylitol) have been studied by N-chlorophthalimide (NCP) in aqueous acetic acid medium in presence of hydrochloric acid at 303 K. The reactions obeyed first-order in [NCP] and fractional-order each in [sugarol] and [H+]. The reactions under investigation follow kobs = c+d [H+] i.e. Bunnett-Olson model. The enhancement in rate was observed in the 10% to 40% (v/v) range of acetic acid. Ru(III) catalyses the reaction at low concentration showing first-order kinetic but declined to follow zero-order at its higher concentration. Michales-Menten equation was verified at transition state for complex. The plausible mechanism was proposed involving HOCl reacting species of oxidant stoichiometrically (1:1) in slow step to yield aldehydes as main products. The thermodynamic parameters and derived rate expression support the mechanism. |
| Keywords: | Sorbitol, Xylitol, N-chlorophthalimide, Ruthenium(III) chloride, Kinetics |
| Cite Article: | "Ruthenium (III) Catalyzed Oxidation of Sugar Alcohols by N-chlorophthalimide", International Journal of Science & Engineering Development Research (www.ijrti.org), ISSN:2455-2631, Vol.8, Issue 1, page no.45 - 49, January-2023, Available :http://www.ijrti.org/papers/IJRTI2301008.pdf |
| Downloads: | 000203 |
| ISSN: |
2456-3315 | IMPACT FACTOR: 8.14 Calculated By Google Scholar| ESTD YEAR: 2016 An International Scholarly Open Access Journal, Peer-Reviewed, Refereed Journal Impact Factor 8.14 Calculate by Google Scholar and Semantic Scholar | AI-Powered Research Tool, Multidisciplinary, Monthly, Multilanguage Journal Indexing in All Major Database & Metadata, Citation Generator |
| Publication Details: |
Published Paper ID: IJRTI2301008
Registration ID:185061
Published In: Volume 8 Issue 1, January-2023
DOI (Digital Object Identifier):
Page No: 45 - 49 Country: -, -, - Research Area: Other Publisher : IJ Publication Published Paper URL : https://www.ijrti.org/viewpaperforall?paper=IJRTI2301008 Published Paper PDF: https://www.ijrti.org/papers/IJRTI2301008 |
| Share Article: | |
|
Click Here to Download This Article |
|
| Article Preview | |
|
|
|
Major Indexing from www.ijrti.org
| Google Scholar | ResearcherID Thomson Reuters | Mendeley : reference manager | Academia.edu |
| arXiv.org : cornell university library | Research Gate | CiteSeerX | DOAJ : Directory of Open Access Journals |
| DRJI | Index Copernicus International | Scribd | DocStoc |
ISSN Details
 |
 |
|
ISSN: 2456-3315
Impact Factor: 8.14 and ISSN APPROVED
Journal Starting Year (ESTD) : 2016
DOI (A digital object identifier)
| Providing A digital object identifier by DOI.ONE How to Get DOI? |
Conference
Open Access License Policy
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License
Important Details
Social Media
Join RMS/Earn 300
Indexing Partner |
|||
| Copyright © 2023 - All Rights Reserved - IJRTI | |||
Facebook Twitter Instagram LinkedIn