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International Journal for Research Trends and Innovation
International Peer Reviewed & Refereed Journals, Open Access Journal
ISSN Approved Journal No: 2456-3315 | Impact factor: 8.14 | ESTD Year: 2016
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Impact Factor : 8.14
Issue per Year : 12
Volume Published : 11
Issue Published : 118
Article Submitted : 21608
Article Published : 8531
Total Authors : 22438
Total Reviewer : 805
Total Countries : 159
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| Paper Title: | Catalysed Oxidation Study of Primary Alcohols (propanol and butanol) by N-chloroisonicotinamide in Aqueous Acetic Acid Medium |
| Authors Name: | Priyanka Singh , Sanjay Kumar Singh |
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| Author Reg. ID: |
IJRTI_185064
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| Published Paper Id: | IJRTI2301011 |
| Published In: | Volume 8 Issue 1, January-2023 |
| DOI: | |
| Abstract: | Keggin-type phosphotungustic acid catalyzed oxidation of (propanol and butanol) by N-chloroisonicotinamide have been investigated in aqueous acetic acid medium in presence of mineral acid H2SO4 to afford corresponding products aldehydes. The redox reaction indicates a first-order dependence in [NCIN] and fractional order on alcohol and PTA. The existence of complex was established and substantiated ted by Michaelis-Menten equation. The variation of H+ ion, isonicotinamide and neutral salts have insignificant effect on rate on oxidation based on observed results two plausible mechanism are postulated one protonated in slow step and the other non-protonated of reacting species in the slow step. The stoichiometry 1:1 and thermodynamic parameters supports the proposed mechanism and rate law. |
| Keywords: | Propanol, Butanol, N-chloroisonicotinamide, Phosphotungustic acid, Kinetics |
| Cite Article: | "Catalysed Oxidation Study of Primary Alcohols (propanol and butanol) by N-chloroisonicotinamide in Aqueous Acetic Acid Medium", International Journal for Research Trends and Innovation (www.ijrti.org), ISSN:2455-2631, Vol.8, Issue 1, page no.60 - 64, January-2023, Available :http://www.ijrti.org/papers/IJRTI2301011.pdf |
| Downloads: | 000205239 |
| ISSN: |
2456-3315 | IMPACT FACTOR: 8.14 Calculated By Google Scholar| ESTD YEAR: 2016 An International Scholarly Open Access Journal, Peer-Reviewed, Refereed Journal Impact Factor 8.14 Calculate by Google Scholar and Semantic Scholar | AI-Powered Research Tool, Multidisciplinary, Monthly, Multilanguage Journal Indexing in All Major Database & Metadata, Citation Generator |
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Published Paper ID: IJRTI2301011
Registration ID:185064
Published In: Volume 8 Issue 1, January-2023
DOI (Digital Object Identifier):
Page No: 60 - 64 Country: -, -, - Research Area: Other Publisher : IJ Publication Published Paper URL : https://www.ijrti.org/viewpaperforall?paper=IJRTI2301011 Published Paper PDF: https://www.ijrti.org/papers/IJRTI2301011 |
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ISSN: 2456-3315
Impact Factor: 8.14 and ISSN APPROVED,
Journal Starting Year (ESTD) : 2016
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