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The oxidative degradation of acrylic acid, and cinnamic acid in aqueous acetic acid, and micellar medium by thallium (III) perchlorate resulted in the formation of the corresponding aliphatic/aromatic aldehydes. The cationic micellar cetyltrimethyl-ammonium bromide (CTAB) has been found to act both as catalysis, and solvent when used under CMC range show non-integral order of reaction. The reactions follow Michaelis-Menen types kinetics. A first-order rate is co-related with rate coefficient, and specific acidity function. A mechanism involving formation of intermediate with CTAB, and Tl+3 reacting species in the slow step has been proposed.
"Study of Kinetics of Electron Transfer reactions between unsaturated Acids and Thallium(III) in Aqueous Acetic Acid and Micellar Medi", International Journal of Science & Engineering Development Research (www.ijrti.org), ISSN:2455-2631, Vol.9, Issue 9, page no.141 - 147, September-2024, Available :http://www.ijrti.org/papers/IJRTI2409022.pdf
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2456-3315 | IMPACT FACTOR: 8.14 Calculated By Google Scholar| ESTD YEAR: 2016
An International Scholarly Open Access Journal, Peer-Reviewed, Refereed Journal Impact Factor 8.14 Calculate by Google Scholar and Semantic Scholar | AI-Powered Research Tool, Multidisciplinary, Monthly, Multilanguage Journal Indexing in All Major Database & Metadata, Citation Generator