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International Journal for Research Trends and Innovation
International Peer Reviewed & Refereed Journals, Open Access Journal
ISSN Approved Journal No: 2456-3315 | Impact factor: 8.14 | ESTD Year: 2016
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Impact Factor : 8.14
Issue per Year : 12
Volume Published : 11
Issue Published : 118
Article Submitted : 21523
Article Published : 8515
Total Authors : 22403
Total Reviewer : 805
Total Countries : 158
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| Paper Title: | N-chlorophthalimide Oxidation of L-Arabinose and D-Xylose in Aqueous Acetic Acid Medium |
| Authors Name: | Surabhi Dwivedi , H.D. Gupta |
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IJRTI_184431
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| Published Paper Id: | IJRTI2212045 |
| Published In: | Volume 7 Issue 12, December-2022 |
| DOI: | |
| Abstract: | The mechanistic study on oxidation of L-arabinose and D-xylose by N- chlorophthalimide in aqueous acetic acid medium has been investigated in 20% aqueous acetic acid medium at 333 K. Reversible formation of reactive intermediates has been observed. The reaction showed first-order dependence in NCP and independent in the ionic strength of the medium with aldose, kinetic evidence support two step reaction mechanism involving a fast pre-equilibrium step followed by a rate determining disproportionation step. Negative value of activation of entropy indicated an ordered transition state for the reaction. The influence of the pentose structure such as steric effect and lengthening of chains on the overall reaction rate were discussed. |
| Keywords: | L-arabinose, D-xylose, N-chlorophthalimide. oxidation, kinetics |
| Cite Article: | "N-chlorophthalimide Oxidation of L-Arabinose and D-Xylose in Aqueous Acetic Acid Medium", International Journal for Research Trends and Innovation (www.ijrti.org), ISSN:2455-2631, Vol.7, Issue 12, page no.345 - 349, December-2022, Available :http://www.ijrti.org/papers/IJRTI2212045.pdf |
| Downloads: | 000205178 |
| ISSN: |
2456-3315 | IMPACT FACTOR: 8.14 Calculated By Google Scholar| ESTD YEAR: 2016 An International Scholarly Open Access Journal, Peer-Reviewed, Refereed Journal Impact Factor 8.14 Calculate by Google Scholar and Semantic Scholar | AI-Powered Research Tool, Multidisciplinary, Monthly, Multilanguage Journal Indexing in All Major Database & Metadata, Citation Generator |
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Published Paper ID: IJRTI2212045
Registration ID:184431
Published In: Volume 7 Issue 12, December-2022
DOI (Digital Object Identifier):
Page No: 345 - 349 Country: -, -, - Research Area: Engineering Publisher : IJ Publication Published Paper URL : https://www.ijrti.org/viewpaperforall?paper=IJRTI2212045 Published Paper PDF: https://www.ijrti.org/papers/IJRTI2212045 |
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ISSN: 2456-3315
Impact Factor: 8.14 and ISSN APPROVED,
Journal Starting Year (ESTD) : 2016
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