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International Journal for Research Trends and Innovation
International Peer Reviewed & Refereed Journals, Open Access Journal
ISSN Approved Journal No: 2456-3315 | Impact factor: 8.14 | ESTD Year: 2016
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Impact Factor : 8.14
Issue per Year : 12
Volume Published : 11
Issue Published : 118
Article Submitted : 21514
Article Published : 8514
Total Authors : 22401
Total Reviewer : 805
Total Countries : 158
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| Paper Title: | Pyridinium Dichromate Oxidation of Ethyl Acetoacetate -A Kinetic Approach |
| Authors Name: | Umakant Sahu , Nagmani Manikpuri |
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| Author Reg. ID: |
IJRTI_184873
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| Published Paper Id: | IJRTI2212098 |
| Published In: | Volume 7 Issue 12, December-2022 |
| DOI: | |
| Abstract: | Pyridinium dichromate (PDC) oxidative study of active methylene compound ethyl acetoacetate (EAA) in acetic acid produces product α-β-diketobutyric acid. A Michaelis-Menten type kinetics was observed for substrate ester while dependency on rate was noticed unity with respect to oxidant PDC. The oxidation kinetics accelerates with increase in proton concentration. The solvent polarity showed that the reaction was of ion-ion dipole type. A mechanism based on measured activation parameters in which rate controlling decomposition of the complex is suggested with a cyclic transition state |
| Keywords: | Pyridinium dichromate, ethyl acetoacetate, oxidation, kinetics, solvent polarity |
| Cite Article: | "Pyridinium Dichromate Oxidation of Ethyl Acetoacetate -A Kinetic Approach", International Journal for Research Trends and Innovation (www.ijrti.org), ISSN:2455-2631, Vol.7, Issue 12, page no.636 - 639, December-2022, Available :http://www.ijrti.org/papers/IJRTI2212098.pdf |
| Downloads: | 000205329 |
| ISSN: |
2456-3315 | IMPACT FACTOR: 8.14 Calculated By Google Scholar| ESTD YEAR: 2016 An International Scholarly Open Access Journal, Peer-Reviewed, Refereed Journal Impact Factor 8.14 Calculate by Google Scholar and Semantic Scholar | AI-Powered Research Tool, Multidisciplinary, Monthly, Multilanguage Journal Indexing in All Major Database & Metadata, Citation Generator |
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Published Paper ID: IJRTI2212098
Registration ID:184873
Published In: Volume 7 Issue 12, December-2022
DOI (Digital Object Identifier):
Page No: 636 - 639 Country: -, -, - Research Area: Engineering Publisher : IJ Publication Published Paper URL : https://www.ijrti.org/viewpaperforall?paper=IJRTI2212098 Published Paper PDF: https://www.ijrti.org/papers/IJRTI2212098 |
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ISSN: 2456-3315
Impact Factor: 8.14 and ISSN APPROVED,
Journal Starting Year (ESTD) : 2016
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