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International Journal for Research Trends and Innovation
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ISSN Approved Journal No: 2456-3315 | Impact factor: 8.14 | ESTD Year: 2016
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Impact Factor : 8.14
Issue per Year : 12
Volume Published : 10
Issue Published : 115
Article Submitted : 19482
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| Paper Title: | Oxidation of n-butanaldehyde by Piperidinium Chlorochromate |
| Authors Name: | Sandeep Kumar Chaurasia , Saras Tiwari |
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| Author Reg. ID: |
IJRTI_187659
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| Published Paper Id: | IJRTI2307081 |
| Published In: | Volume 8 Issue 7, July-2023 |
| DOI: | |
| Abstract: | The highly toxic chromium (VI) compounds are converted into eco-friendly non-toxic chromium (III) compounds by using several oxidants. One such compound is piperidinium chlorochromate, used as an oxidant to oxidize n-butanaldehyde in 60% aqueous acetic acid medium in presence of H+ ions. The rection proceeds through the reversible complexation between the keto n-butanldehyde and protonated reacting species of oxidant, which disproportionates via a cyclic transition state in a rate-determining step, to yield the product n-butyric acid. The reaction was of first-order with respect to Pipcc. And fractional-order to hydrogen ion. However, Michaelis-Menten type kinetics was observed in n-butanaldehyde. A carbo cationic species thorough hydride-ion transfer from n-butanaldehyde to oxidant (Pipcc.) was suggested in mechanism. |
| Keywords: | n-butanaldehyde, Piperidinium chlorochromate, kinetics, oxidation, stoichiometry |
| Cite Article: | "Oxidation of n-butanaldehyde by Piperidinium Chlorochromate", International Journal of Science & Engineering Development Research (www.ijrti.org), ISSN:2455-2631, Vol.8, Issue 7, page no.551 - 554, July-2023, Available :http://www.ijrti.org/papers/IJRTI2307081.pdf |
| Downloads: | 000205247 |
| ISSN: |
2456-3315 | IMPACT FACTOR: 8.14 Calculated By Google Scholar| ESTD YEAR: 2016 An International Scholarly Open Access Journal, Peer-Reviewed, Refereed Journal Impact Factor 8.14 Calculate by Google Scholar and Semantic Scholar | AI-Powered Research Tool, Multidisciplinary, Monthly, Multilanguage Journal Indexing in All Major Database & Metadata, Citation Generator |
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Published Paper ID: IJRTI2307081
Registration ID:187659
Published In: Volume 8 Issue 7, July-2023
DOI (Digital Object Identifier):
Page No: 551 - 554 Country: -, -, India Research Area: Chemistry Publisher : IJ Publication Published Paper URL : https://www.ijrti.org/viewpaperforall?paper=IJRTI2307081 Published Paper PDF: https://www.ijrti.org/papers/IJRTI2307081 |
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ISSN: 2456-3315
Impact Factor: 8.14 and ISSN APPROVED,
Journal Starting Year (ESTD) : 2016
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