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This paper reports the kinetics of oxidation of diols such as þentane-1,5-diol, hexane 1,6-diol by isoquinolinium chlorochromate in aqueous acetic acid medium under first-order kinetic conditions with respect to oxidant. The study reveals the existence of complex formation between substrate and oxidant at the transition point. The study determined the ionic strength of the medium. The substrates follow the sequence hexane- 1,6-diol > Pentane1,5-diol for all the alcohols studied. The thermodynamic parameters have been interpreted in terms of the molecular dynamics and reaction mechanism suggested for the proton abstraction in the oxidation process.
"Kinetic Study of Oxidation of Some Diols by Isoquinolinium Chlorochromate in Aqueous Acetic acid Medium", International Journal for Research Trends and Innovation (www.ijrti.org), ISSN:2456-3315, Vol.8, Issue 7, page no.555 - 558, July-2023, Available :http://www.ijrti.org/papers/IJRTI2307082.pdf
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2456-3315 | IMPACT FACTOR: 8.14 Calculated By Google Scholar| ESTD YEAR: 2016
An International Scholarly Open Access Journal, Peer-Reviewed, Refereed Journal Impact Factor 8.14 Calculate by Google Scholar and Semantic Scholar | AI-Powered Research Tool, Multidisciplinary, Monthly, Multilanguage Journal Indexing in All Major Database & Metadata, Citation Generator